楊則恆
人物履歷
1978年9月–1982年7月,合肥工業大學化工系無機化工專業學習,獲(工學學士)學位;
1988年9月–1991年4月,合肥工業大學化工系應用化學專業學習,獲(工學碩士)學位;
2003年2月–2005年11月,中國科學技術大學化學與材料科學學院無機化學專業學習,獲(理學博士)學位;
1982年7月–1988年8月,合肥化工廠工作,擔任技術員;
1991年4月–1999年12月,安徽地質實驗研究所工作,1997年晉升高級工程師;
2008年1月–2009年1月,澳大利亞悉尼大學,化工與分子生物工程學院,訪問學者;
2000年1月–至今,合肥工業大學工作,化學與化工學院,教授(2007年)、博士生導師(2012年)。
研究領域
1、鋰離子電池、超級電容器等電極材料製備與應用研究
2、納米功能材料製備、表徵及應用基礎研究
研究成果
長期從事鋰離子電池、超級電容器等能量存儲與轉換器件電極材料的設計、製備過程技術、性能調控與產業化關鍵技術研發。主持承擔國家級、省部級與企業委託科研課題10多項。發表SCI收論文90餘篇,獲授權發明專利15項。曾獲安徽省科學技術二等獎。
科研項目
主持承擔及完成的主要項目:
(1) 退役磷酸鐵鋰動力電池的梯次利用與回收處理關鍵技術研發及產業化應用, 安徽省科技重大專項項目,校內主持人,2019.7-2022.6
(2)三元正極材料用多段燒結爐結構設計研究,界首市南都華宇電源有限公司委託項目,主持人,2020.5-2023.5
(3)動力型鋰離子電池鎳鈷錳酸鋰(NCM622)三元正極材料製備關鍵技術研發,銅陵金泰電池材料有限公司委託項目,主持人,2017.9-2018.12
(4) 二次電池高比容量負極材料開發,奇瑞汽車股份有限公司委託項目,主持人,2014.10-2016.9
(5)基於水熱反應修復廢舊磷酸鐵鋰正極材料及其性能改善研究,國家自然科學基金,主持人,2012.1-2015.12
(6)基於廢舊錳酸鋰電極材料原位製備不同晶型與形貌的MnO2及其應用基礎研究,國家自然科學基金,主持人,2010.1-2012.12
(7)基於廢舊鋰離子電池電極材料LiMn2O4原位製備高效MnO2催化劑,國家自然科學基金,主持人,2009.1-2009.12
(8)Fe2+/介孔結構錳氧化物複合催化劑製備及其催化降解有機物廢水的協同作用研究,安徽省基金,主持人,2007.1-2008.12
(9)一維富鋰錳基正極材料介尺度結構演化過程機制與調控規律,國家自然科學基金,第二承擔人,2016.1-2018.12
(10)錳氧化物納米結構催化劑的控制合成及其在染料廢水降解處理中的應用基礎研究,國家自然科學基金,第二承擔人,2006.1-2008.12
獲獎情況
獲獎:
(1) 安徽省教學成果獎特等獎(第一完成人,2019年)
(2) 安徽省科學技術二等獎(第二完成人,2007年)
專利:
(1)張衛新,楊則恆,李文明,陳飛,王業波. 「一種多孔結構開口核桃殼狀鈉離子電池正極材料及其製備方法」, ZL201910525450.5.
(2) 楊則恆,呂洪,張衛新,熊凡,王業波,「一種綜合回收再利用廢舊三元電極材料的方法」,ZL201820313501.9.
(3)張衛新,熊凡,楊則恆,陳章賢,「一種基於近化學平衡體系製備鈦酸鋰包覆高鎳三元正極材料的方法」, ZL201910369581.9.
(4) 陳章賢,唐偉建,楊則恆,張衛新.「一種基於均相共沉澱體系製備鋁酸鋰包覆鋰離子電池富鋰材料的方法」,ZL201810921048.4.
(5)張衛新,楊則恆,李文明,陳飛,王業波. 一種用於焙燒鋰離子電池電極材料的排氣與傳熱多功能裝置,ZL201820313501.9.
(6)楊則恆,劉樹林,李昇,馬國,張衛新等,「一種長徑比可調的一維微納結構錳基鋰離子電池電極材料的通用製備方法」,ZL201610074122.4.
(7)楊則恆,陸劍波,張衛新,馬國,張偉波等,「一種多孔棒狀結構鈷基鋰離子電池正極材料的製備方法」 ,ZL201410166626.X.
(8)楊則恆,翁紹迎,張衛新,王強,裴波. 「一種廢舊磷酸鐵鋰電池正極材料修復再生的方法」,ZL201110121896.5.
(9)張衛新,曾暉,楊則恆,王強,陳公德. 「一種在銅基底上製備鋰離子電池電極材料CuO薄膜的方法」,ZL201110132431.X.
(10)張衛新,張曉靜,楊則恆. 「一種羥基磷灰石納米結構微球的製備方法」,ZL201110122427.5.
(11)楊則恆,張衛新,馬世闖,周晨旭,王強. 「一種自廢舊錳酸鋰電池正極材料中回收MnO2的方法及其應用」,ZL200910116656.9.
(12)張衛新,楊則恆,王強,王華. 「一種鋰離子電池用磷酸亞鐵鋰正極材料及改性方法」,ZL200810122605.2.
(13)張衛新,楊則恆,王強,劉怡. 「一種鋰離子電池用系列納米鋰錳氧化物的合成方法」,ZL200610038148.X.
(14)張衛新,楊則恆,丁篩霞,楊世和. 「氧化銅納米管陣列的製備方法」,ZL200610037649.6.
(15)張衛新,楊則恆,張願成等. 「亞甲基藍染料廢水處理方法及催化劑製備方法」,ZL200510122782.7.
著作論文(代表作)
[1] Engineering superhydrophilic/superaerophobic hierarchical structures of Co-CH@NiFe-LDH/NF to boost the oxygen evolution reaction. Chemical Engineering Journal, 2021, 422, 130123. Shuai Cao, Haijian Huang, Kun Shi, Li Wei, Ning You, Xiaoming Fan, Zeheng Yang*, Weixin Zhang*.
[2] Electric field driven de-lithiation: A strategy towards comprehensive and efficient recycling of electrode materials from spent lithium ion batteries. Applied Catalysis B: Environmental, 2021, 283, 119634. Hong Lv#, Haijian Huang#, Cheng Huang, Qiang Gao, Zeheng Yang*, Weixin Zhang*.
[3] Novel hierarchical yolk-shell α-Ni(OH)2/Mn2O3 microspheres as high specific capacitance electrode materials for supercapacitors. Frontiers of Chemical Science and Engineering, 2021, In press. Xiqing Luo, Miaomiao Jiang, Kun Shi*, Zhangxian Chen, Zeheng Yang*, Weixin Zhang*.
[4] CoP microscale prism-like superstructure arrays on Ni foam as an efficient bifunctional electrocatalyst for overall water splitting. Inorganic Chemistry, 2020, 59, 8522-8531. Shuai Cao, Ning You, Li Wei, Cheng Huang, Xiaoming Fan, Kun Shi, Zeheng Yang*, Weixin Zhang*.
[5] Multi-shelled Ni6MnO8 hollow microspheres for high-performance supercapacitors. Materials Research Express, 2020, 7, 065502. Xiaoyu Liu, Jun Cao, Cheng Huang, Zhangxian Chen, Xiaoming Fan, Kun Shi, Zeheng Yang*, Weixin Zhang*.
[6] Near-equilibrium control of Li2TiO3 nanoscale layer coated on LiNi0.8Co0.1Mn0.1O2 cathode materials for enhanced electrochemical performance. Inorganic Chemistry, 2019, 58, 15498-15506. Fan Xiong, Zhangxian Chen, Cheng Huang, Tongzhen Wang, Weixin Zhang*, Zeheng Yang*, Fei Chen.
[7] An effective etching-induced coating strategy to shield LiNi0.8Co0.1Mn0.1O2 electrode materials by LiAlO2. Journal of Power Sources, 2019, 412, 246-254. Weijian Tang, Zhangxian Chen*, Fan Xiong, Fei Chen, Cheng Huang, Qiang Gao, Tongzhen Wang, Zeheng Yang*, Weixin Zhang*.
[8] 片狀LiFePO4/C正極材料製備及其電化學性能研究. 化工學報,2019, 70, 1628-1634. 高強,呂洪,熊凡,陳飛,楊則恆*,張衛新.
[9] Sequential precipitation induced interdiffusion: a general strategy to synthesize microtubular materials for high performance lithium ion battery electrodes. Journal of Materials Chemistry A, 2018, 6, 18430-18437. Fei Chen, Weixin Zhang*, Junrui Fu, Zeheng Yang, Xiaoming Fan, Weibo Zhang, Zhangxian Chen, Mengqiu Huang, Shihe Yang*.
[10] Hierarchical micro/nanostructured WO3 with structural water for high-performance pseudocapacitors. Journal of Alloys and Compounds, 2018, 765: 489-496. Zongming Shao, Xiaoming Fan, Xiaoyu Liu, Zeheng Yang*, Lei Wang, Zhangxian Chen, Weixin Zhang.
[11] 基於分級共沉澱法製備鋰離子電池LiNi0.5Co0.2Mn0.3O2正極材料. 化工學報, 2017, 68, 1239-1246. 夏青, 趙俊豪, 王凱, 李昇, 郭冰, 田院, 楊則恆, 張衛新*.
[12] Aluminum and fluorine co-doping for promotion of stability and safety of lithium-rich layered cathode material. Electrochimica Acta, 2017, 236, 171-179. Bing Guo, Junhao Zhao, Xiaoming Fan, Wei Zhang, Sheng Li, Zeheng Yang*, Zhangxian Chen, Weixin Zhang*.
[13] A novel process to recycle spent LiFePO4 for synthesizing LiFePO4/C hierarchical microflowers. Electrochimica Acta, 2016, 190, 134-140. Doucheng Bian, Yonghui Sun, Sheng Li, Yuan Tian, Zeheng Yang*, Xiaoming Fan, Weixin Zhang*.
[14] Synthesis of Ti3+ self-doped TiO2 nanocrystals based on Le Chatelier's principle and their application in solar light photocatalysis. RSC Advances, 2016, 6, 74376-74383. Maoqin Qiu, Yuan Tian, Zhangxian Chen*, Zeheng Yang*, Wenming Li, Kai Wang, Lei Wang, Kun Wang, Weixin Zhang*.
[15] pH-controlled assembly of three-dimensional tungsten oxide hierarchical nanostructures for catalytic oxidation of cyclohexene to adipic acid. CrystEngComm. 2016, 18, 8688-8695. Lei Wang, Mengqiu Huang, Zhangxian Chen, Zeheng Yang*, Maoqin Qiu, Kai Wang, Weixin Zhang*.
[16] Kinetically controlled synthesis of LiNi0.5Mn1.5O4 micro- and nanostructured hollow spheres as high-rate cathode materials for Lithium ion batteries. Industrial & Engineering Chemistry Research, 2016, 55, 9352-9361. Sheng Li, Guo Ma, Bing Guo, Zeheng Yang*, Xiaoming Fan, Zhangxian Chen, Weixin Zhang*.
[17] A general and mild approach to controllable preparation of manganese-based micro- and nanostructured bars for high performance lithium-ion batteries. Angewandte Chemie International Edition, 2016, 55(11): 3667-3671. Guo Ma#, Sheng Li#, Weixin Zhang*, Zeheng Yang, Shulin Liu, Xiaoming Fan, Fei Chen, Yuan Tian, Weibo Zhang, Shihe Yang*, Mei Li.
[18] 廢舊LiFePO4正極材料的循環利用及電化學性能. 硅酸鹽學報, 2015, 43, 1511-1516. 卞都成, 劉樹林, 孫永輝, 楊則恆*.
[19] Self-sustained cycle of hydrolysis and etching at solution/solid interfaces: a general strategy to prepare metal oxide micro/nanostructured arrays for high-performance electrodes. Angewandte Chemie International Edition, 2015, 54, 3932-3936. Yingmeng Zhang, Weixin Zhang*, Zeheng Yang, Heyun Gu, Qing Zhu, Shihe Yang*, Mei Li.
[20] A new lithium-ion battery: CuO nanorod array anode versus spinel LiNi0.5Mn1.5O4 cathode. Journal of Power Sources, 2015, 273, 561-565. Weixin Zhang*, Guo Ma, Heyun Gu, Zeheng Yang, He Cheng.
[21] Solvothermal synthesis of hierarchical LiFePO4 microplates with exposed (010) faces as cathode materials for lithium ion batteries. Industrial & Engineering Chemistry Research, 2014, 53, 12209-12215. Jun Zhang, Jianbo Lu, Doucheng Bian, Zeheng Yang*, Qing Wu, and Weixin Zhang*.
[22] An improved solid-state reaction route to Mg2+-doped LiFePO4/C cathode material for Li-ion battery. Ionics, 2014, 20, 169-174. Zeheng Yang*, Jianfeng Xia, Lihua Zhi, Weixin Zhang, and Bo Pei.
[23] Hydrothermal synthesis of Fe5(PO4)4(OH)3•2H2O microflowers for fabricating high-performance LiFePO4/C composites. Ionics, 2014, 20, 653-658. Zeheng Yang*, Jun Zhang, Qing Wu, Weixin Zhang, and Hui Wang.
[24] Stepwise co-precipitation to synthesize LiNi1/3Co1/3Mn1/3O2 one-dimensional hierarchical structure for lithium ion batteries. Journal of Power Sources, 2014, 272, 144-151. Zeheng Yang, Jianbo Lu, Doucheng Bian, Weixin Zhang*, Xiaoning Yang, Jianfeng Xia, Gongde Chen, Heyun Gu and Guo Ma.
[25] Controllable preparation of multishelled NiO hollow nanospheres via layer-by-layer self-assembly for supercapacitor application. Journal of Power Sources, 2014, 26, 24-31. Zeheng Yang, Feifei Xu, Weixin Zhang*, Bo Pei, and Xiao Zhu.
[26] Facile synthesis of mesoporous MnO2/C spheres for supercapacitor electrodes. Chemical Engineering Journal, 2014, 242, 397-403. Yanmei Pan, Zhousheng Mei, Zeheng Yang*, Weixin Zhang, Bo Pei, and Hongxu Yao.
[27] An outward coating route to CuO/MnO2 nanorod array films and their efficient catalytic oxidation of acid fuchsin dye. Industrial & Engineering Chemistry Research, 2014, 53, 9608-9615. Zeheng Yang*, Yumei Yang, Xiao Zhu, Gongde Chen, and Weixin Zhang*.
[28] Chemical replacement route to Cu2-xSe-coated CuO nanotube array anode for enhanced performance in lithium ion batteries, Journal of Materials Chemistry A, 2014, 2, 5800-5808. Weixin Zhang*, Zaoyuan Zhou, Wenran Zhao, Zeheng Yang, and Xiaoning Yang.
[29] Different types of MnO2 recovered from spent LiMn2O4 batteries and their application in electrochemical capacitors. Journal of Materials Science, 2013, 48, 2512-2519. Zeheng Yang, Zhousheng Mei, Feifei Xu, Yunjin Yao, Weixin Zhang*, Wencong Qi, Qiuli Song, Zhuwei Gao, Tuan Zhao.
[30] A carbothermal reduction method for enhancing the electrochemical performance of LiFePO4/C composite cathode materials. Ionics, 2013, 19, 235-243. Shaoying Weng, Zeheng Yang*, Qiang Wang, and Weixin Zhang.
[31] Cosurfactant-mediated microemulsion to free-standing hierarchical CuO arrays on copper substrates as anodes for lithium-ion batteries. Journal of Materials Chemistry A, 2013, 1, 14368-14374. Yingmeng Zhang, Weixin Zhang*, Mei Li, Zeheng Yang, Gongde Chen, Qiang Wang.
[32] Preparation of mesoporous MnO2/C catalyst for n-hexyl acetate synthesis. Appl. Surf. Sci., 2012, 162, 292-299. Zeheng Yang*, Yanmei Pan, Zhousheng Mei, and Weixin Zhang.
[33] Hydrothermal synthesis of morphology-controlled LiFePO4 cathode material for lithium-ion batteries. Journal of Power Sources, 2012, 220, 317-323. Bo Pei, Hongxu Yao, Weixin Zhang*, and Zeheng Yang.
[34] Solvothermal synthesis of hierarchical LiFePO4 microflowers as cathode materials for lithium ion batteries. Journal of Power Sources, 2011, 196(23): 10176-10182. Qiang Wang, Weixin Zhang*, Zeheng Yang, Shaoying Weng, Zhuojie Jin.
[35] Hierarchical self-assembly of microscale cog-like superstructures for enhanced performance in lithium-ion batteries. Advanced Functional Materials, 2011, 21(18): 3516-3523. Weixin Zhang, Mei Li, Qiang Wang, Gongde Chen, Mei Kong, Zeheng Yang, Stephen Mann*.[1]