檢視彭以元的原始碼

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'''彭以元'''，男，[[博士]]，1964年2月生。 [[致公党]]，[[江西师范大学]]化学学院、生命科学学院二级[[教授]]，化学生物学[[博士生导师]]<ref>[http://school.freekaoyan.com/jiangxi/jxnu/daoshi/2021/05-04/16201379431446520.shtml   江西师范大学化学化工学院导师教师师资介绍简介-彭以元（教授） ],江西师范大学, 2021-05-04</ref>;有机化学、应用化学、生物科学、生态学、生物化工[[硕士]]生导师。担任江西师范大学化学化工学院院长<ref>[https://www.jju.edu.cn/info/1048/51899.htm   江西师大化工学院来到化环学院开展考研宣传活动 ],九江学院, 2016-05-29</ref>、功能有机小分子教育部重点实验室主任、 [[江西省]]绿色化学重点实验室主任。入选江西省新世纪百千万人才工程，江西省高等学校中青年学科带头人<ref>[https://yz.kaoyan.com/jxnu/daoshi/24/509935/   江西师范大学生命科学学院导师介绍：彭以元 ],江西师范大学, 2013-08-24</ref>、江西省省人民政府学科评议组成员，赣鄱"555"领军人才<ref>[https://chem.jxnu.edu.cn/2011/1121/c10079a78823/page.htm   彭以元（教授） ],江西师范大学, 2019-01-18</ref>。

==基本信息==
人物说明----江西师范大学化学化工学院院长

出生日期----1964年2月

出生地点----江西吉水

国   籍 ----  中国

职   业 ----  教育科研管理工作者

毕业院校----江西师范大学

==主要经历==
1981.9~1985.7 在江西师范大学化学系学习，1985年大学本科毕业。

1985.9~1988.12 在上海有机化学研究所攻读硕士研究生，师从蒋锡夔院士和赵成学教授，毕业论文题目为:伯胺氧化生成含氟氮氧自由基的方法、反应机理。

1988.12~1990.4 在上海有机所从事研究工作。

1990.5~1994.6 在江西省化工研究所从事有机硅产品开发、应用研究。

1995.7~2000.9 在江西师范大学化学系，从事有机硅化学、含氟氮氧自由基化学和量子化学计算的基础研究和教学工作。

2000.9~2003.6 在南开大学化学学院化学系读在职博士。

2003.7~2009.2 在江西师范大学化学化工学院工作，从事有机硅化学、绿色化学、化学生物学研究。

2009.3~ 在江西师范大学生命科学学院从事教学科研工作。

==职称情况==
1992年被聘为工程师。

1996年被破格评聘为副教授，有机化学硕士研究生导师。

2001年被破格评聘为教授。

==科研成果==
获得三个国家自然科学基金和一个国际合作项目资助。共完成省部级以上项目十余项，如下:

'''Ⅰ.已完成的省科委下达的技术重点项目'''

1. 2004 年负责完成江西省重点攻关项目:织物整理剂--有机氟硅乳液的研制

2. 1998-2000年负责完成江西省重点攻关项目: KBM802及巯基改性硅油的研制

3. 1996 –1997年负责完成江西省重点项目: 硅偶联剂KBM602、KBM603的合成
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4. 1995~1996年负责完成省计委扶贫项目:黄麻纤维板材及其制品的研制

5. 1993~1994年负责完成江西省一级重点项目:氨基改性硅油的研制

6. 1992~1993年参与并完成两项新药物中间体的研制:脒基硫脲和1,3-二氯丙酮的小试研制和工业化中试生产

7. 1990~1991年参与完成江西省重点攻关项目:高温硫化硅橡胶的研制，该项目获江西省科技进步二等奖。

'''Ⅱ.已完成的基础研究项目'''

1. 2008年完NIH(国家卫生局)开放基金项目:脑蛋白凝聚机理、诊断及其成像剂研究

2. 2007年完成国家自然科学基金项目: 绿色溶剂中氨基酸及多肽催化不对称直接催化aldol类反应

3. 2004年完成国家自然科学基金项目:水相及胶束中氨基酸及多肽直接催化aldol类反应

4. 2004年南开大学元素有机国家重点实验室开放基金项目:水相中氨基酸催化aldol 反应研究

5. 2001~2003负责江西省自然科学基金项目:有机硅树脂支持的合成反应

6. 1997~1998年负责完成江西省青年基金项目:新型氮氧自由基的结构与性能研究。

'''Ⅲ.正在负责的在研项目'''

1.负责江西省重点工业攻关项目:有机硅氟攻性材料的研制

2.国家自然科学基金项目:神经退化疾病中的α-synuclein淀粉蛋白质小分子探针的研究

3.省自然科学基金项目:α-synuclein淀粉蛋白质小分子探针合成

4.9省教委教改课题: 础化学实验一体化课程改革及教材建设研究项目资助通知;

==教学情况==
'''Ⅰ.开设研究生课'''

1. 研究生课: 《有机结构分析--波谱解析》

2. 研究生课: 《量子有机化学》

3. 研究生基础课 《有机化学合成》

4. 研究生基础课 《不对称合成》

5. 研究生专业课 《化学生物学》

'''Ⅱ.开设的本科教学课程'''

1. 本科生基础课《有机化学》

2. 本科生基础课《有机化学实验》

3. 本科基础课:《结构化学》

4. 本科必选课: 《有机合成》

5. 本科选修课: 《现代分子结构测定的原理与方法》

6. 本科选修课: 《绿色化学概论》

'''Ⅲ. 共培养了22名硕士研究生'''。

==所获荣誉==
1. 2000年获上海市科技进步三等奖。

2. 江西省政协委员

3. 国际期刊Tetrahedron: Asymmetry 通信评委

==最近发表论==
1. Ligand-Free Copper-Catalyzed One-Pot Synthesis of Indole-2-carboxylic Esters, Eur. J. Org. Chem. 2014, 511-514.

2. Cross-coupling/annulations of quinazolones with alkynes for access to fused polycyclic heteroarenes under mild conditions, Org. Biomol. Chem., 2014，12，758-764.

3. Palladium-Catalyzed Cyanation of Quinazoline-4-tosylates forAccess to 4-CN Functionalized Quinazolines, Synthesis 2013, 45, 3245-3250.

4. Syntheis of 4-arylquinazolines by Arylation of 4- Arylquinazolinones under mild conditions Synthesis 2013, 45, 3131-3136.

5. Synthesis of 4-Sulfanylcoumarins Using Thiourea and Alkyl Halides as the Sulfanylation Agent in Polyethylene Glycol-Water Synthesis 2013, 45, 759-766.

6. Palladium-catalyzed direct ortho-acylation through an oxidative coupling of 2-arylbenzothiazoles with benzylic alcohols Tetrahedron 2013，69，8661-8667.

7. Palladium-catalyzed C-H bond functionalization/oxidative acyloxylation of 2-aryl-benzo[d]thiazoles, J. Organometallic Chem2013, 739, 33-39

8. New simple synthesis of ring-fused 4-alkyl-4H-3,1-benzothiazine-2-thiones: Direct formation from carbon disulfide and (E)-3-(2-aminoaryl)acrylates or (E)-3-(2-aminoaryl)acrylonitriles Beilstein J. Org. Chem. 2013, 9, 460-466.

9. Dual effects of (t)-catechin on hemin-induced oxidative reactions: A potential pharmacological implication Free Radicals and Antioxidants, 2013 3 11-16.

10. Effects of quercetin on hemoglobin-dependent redox reactions relationship to iron-overload rat liver injury, J. Asian Natural Products Research, 2013,15,1265-1276.

11. Construction of heterocyclic scaffolds via transition metal-catalyzed sp3 C-H functionalization J. Organometallic Chem2013, 723, 224-232

12. Metal Co-Catalyzed Tandem Alkynylative Cyclization Reaction of in situ formed N-Iminoisoquinolinium Ylides with Bromoalkynes via C-H Bond Activation, J. Organic Chem.2012, 77,8092-8098.

13. N-Heterocyclic Carbene Catalyzed One-Pot Synthesis of 2,3-Diarylquinoxalines Sythesis 2012, 44, 2699-2706

14. Silver Triflate and Palladium Acetate Co-catalyzed Reaction of N-(2-Alkynylbenzylidene)hydrazide with N-Allyl Ynamid Org Lett. 2012, 14, 2790-2793.

15. Novel Silver Tetrafluoroborate Catalyzed Electrophilic Cascade Cyclization Reaction: A Facile Approach to the Synthesis of Halo-Substituted Benzo[a]fluorenols, Org Lett. 2012, 14, 3588-3590.

16. Direct Sulfanylation of 4-Quinazolinone via C–OH Bond Activation: An Efficient Route to 2-Aryl-4-sulfanylquinazolines Sythesis 2012, 44, 1237-1246.

17. Enhancement of nitrite on heme-induced oxidative reactions: A potential toxicological implication, Toxicology in Vitro 2012,26, 81-85.

18. Synthesis of 1,3-Dihydrobenzo[c]thiophene-imines via Tandem Reactions of o-(1-Alkynyl)benzamides and Lawesson's Reagent, Sythesis 2012, 44, 920-926.

19. One-pot two-step synthesis of 1-position arylated 1,3-disubstituted isoquinoline N-oxides Tetrahedron 2012，68 ,8869-8874.

20. Access to functionalized 4-benzylidene-4H-benzo[d][1,3]thiazines via tandem addition-cyclization/cross-coupling reactions Tetrahedron 2012，68，3937-3941.

21. Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodide via benzothiazole-directed C-H activation.Journal of Organometallic Chemistry 2012，711, 62-67.

22. Facile assembly of cyclopenta[c]quinolin-3-ols via a palladium-catalyzed reaction of 2-alkynylaniline with 2-alkynylvinyl bromide Tetrahedron 2012，68，9004-9008.

23. Synthesis of 4-methylene-4H-benzo[d][1,3]thiazines via a tandem reaction of 1-(2-alkynylphenyl)ketoximes with Lawesson's reagent, Chem. Commun. 2011 9708–9710.

24. Rapid access to 4-substituted-pyrones and 2(5H)-furanones via a palladiumcatalyzed CeOH bond activation Tetrahedron 2011，67， 7258-7262

25. An efﬁcient approach to pyrazolo[5,1-a]isoquinolin-2-amines via a silver(I)-catalyzed three-component reaction of 2-alkynylbenzaldehyde, sulfonohydrazide, and nitrile Org. Biomol. Chem., 2011 7033-7037

26. Generation of diverse 2-pyrones via palladium-catalyzed site-selective Suzuki-Miyaura couplings of 3-bromo-4-tosyloxy-2-pyrone Org. Biomol. Chem., 2011，9，6265-6270

27. Efficient Assembly of 1-(1H-Imidazol-1-yl)-3-methylene-1H-indenes via Tandem Reaction of (2-(Alkynyl)benzylidene)malonates with Imidazoles Combinatorial Science, 2011, 13, 13-18

28. Generation of 3-(1H-Isochromen-1-yl)-1H-indole via Silver Triflate-Catalyzed Tandem Reaction of 2-Alkynylbenzaldehyde with Indole, Heterocycles 2011, 82, 1239-1249.

29. Cationic Micelle-catalyzed Ring-Opening Reactions of Aziridines with Thiols in Water Chinese Journal of Chemistry 2011, 29,499-503·

30. Aqueous C-S cross-coupling:synthesis of 2-iminobenzo-1,3-oxathioles via CuCl2·H2O -catalyzed tandem reaction of 2-iodophenols with isothiocyanates Tetrhedron lett. 2011, 52, 1964-1967.

31. Synthesis of thioethers via metal-free reductive coupling of tosylhydrazones with thiols· Org. Biomol. Chem., 2011, 9, 748–751.

32. Iron-catalyzed tandem reactions of ortho-aminobenzenethiols with isothiocyanates leading to 2-aminobenzoazoles under ligandand solvent-free conditions, Phosphorus, Sulfur, and Silicon, 2011, 186, 1782–1789.

33. Effects of glutathione, Trolox and desferrioxamine on hemoglobin-induced protein oxidative damage: anti-oxidant or pro-oxidant· European Journal of Pharmacology，2011，659，95-101

34. Anti- and pro-oxidant effects of (+)-catechin on hemoglobin-induced protein oxidative damage·Toxicology in Vitro, 2011, 52,833-838·

35. Pyridine-N-oxide: An Efficient Organocatalyst for Ring-Opening Reactions of Aziridines with Thiols，Chinese Journal of Chemistry 2011, 29,79-84

36. Pyridinium tribromide catalyzed condensation of indoles and aldehydes to form bisindolylalkanes Chinese Chemical letters, 2011, 22,515-518

37. Multicatalytic One-Pot Reaction of 1-(2-Alkynylphenyl)ketoximes for Generation of Indole Derivatives， Orglett. 2010, 12, 3975-3977.

38. Synthesis of 2-aminobenzothiazole via FeCl3-catalyzed tandem reaction of 2-iodoaniline with isothiocyanate in water·Green chemistry 2010, 12,1607-1610·

39. Room-Temperature Highly Efficient Suzuki-Miyaura Reactions in Water in the Presence of Stilbazo，Green chemistry 2010,12, 1072-1075.

40. Silica Gel-Promoted Tandem Addition Cyclization Reactions of 2-Alkynylbenzenamines with Isothiocyanates· J. Comb. Chem. 2010, 12, 370–373.

41. Iron-Catalyzed one-pot synthesis of 2-aminobenzothiazoles from 2-aminobenze -thiols and isothiocynates under ligand-free conditions in water. Heterocycles 2010,81, 2841-2847.

42. A convenient one-pot procedure for the synthesis of 2-aryl quinazolines using active MnO2 as oxidant，J. Heterocycl. Chem. 2010, 47，1240-1245.

43. Synthesis of (Z)-1-benzylidene-3-(1H-indol-1-yl)-1H-indene-2,2(3H)-dicarbonitriles via three-component reaction of of 2-alkynylbenzaldehyde, malononitrile, and indole Tetrhedron lett. 2010, 51, 4391-4394.

44. 无溶剂条件下脯氨酸甲酯催化syn选择性羟醛缩合反应 有机化学, 2010, 30, 389-394.

45. An efficient route to 4-substituted coumarins, 2(5H)-furanones, and pyrones via palladium-catalyzed couplings of alkenyl tosylates with organoindium reagents Tetrhedron lett. 2010, 51, 136-138.

46. Direct Sulfanylation of 4-Hydroxycoumarins with Thiols in Water Tetrahedron Lett. 2009, 50, 2405-2406.

47. Highly efficient electrophilic cyclization of N-(2-alkynylbenzylidene)hydrazides, Tetrahedron Lett. 2009, 50, 340-342.

48. Highly efficient N-monomethylation of primary aryl amines Chinese Journal of Chemistry 2009, 27,1339-1344.

49. A Facile Aqueous Synthesis of Bis(indol-3-yl)alkanes Catalyzed by Dodecylbenzenesulfonic acid Chinese Journal of Chemistry 2008, 26, 2228-2232.

50. Arginine Catalyzed Direct Aldol Reactions in Pure Water:An Environmentally Friendly Reaction System Chinese Journal of Chemistry 2008, 26,1454-1460.

51. Asymmetric Synthesis of Bicyclic Piperidines via L-Proline Catalyzed Aldol Reaction of 3-Phthalimidopropanal Chrality，2008，20，805-801.

52. Pyrrolidine as an efficient organocatalyst for direct aldol reaction of trifluoroacetaldehyde ethyl hemiacetal with ketones Tetrahedron 2007, 63, 4636–4641.

53. L-Prolinamide Catalyzed Aqueous Direct Aldol Reaction: an Environment-friendly Method for the Synthesis ofβ-Hydroxylketones Chinese Journal of Chemistry, 2007，25，962-957.

54. An Environmentally Benign System for Synthesis of β-Hydroxylketones: L-Histidine Asymmetrically Catalyzed Direct Aldol Reactions in Aqueous Micelle and Water-like Media, Chinese Journal of Chemistry, 2007, 25, 356-363.

55. Cai ,L. S.; Cuevas, J.; Peng, Y. Y.; Pike V. W. Rapid palladium-catalyzed cross-coupling in the synthesis of aryl thioethers under microwave conditions. Tetrahedron Letters 2006, 47, 4449–4452.

56. 丁酮与硝基苯甲醛反应生成的 aldol 产物的NMR 表征方法及其应用 江西师范大学学报(自然科学版) 2006, 30， 141-144。

57. Proline Catalyzed Aldol Reactions in Aqueous Micelles: An Environmentally Friendly Reaction System Tetrahedron letter 2003 3871-3875.

58. The trifluoromethylation of 1,1-dibromo-1-alkenes using trifluoromethyl--copper (CF3Cu) generated in situ from methyl fluorosulfonyldifluoroacetate Journal of Fluorine Chemistry 2001, 111, 185-1873.

59. The sterospecific trifluoromethylation of α-iodo-α,β-unsaturated esters: a novel synthesis of (Z)-α-trifluoromethyl-α,β-unsaturated esters Journal of Fluorine chemistry 2001,108, 79~82

60. . ESR studies on the solvation of perfluoro-n-alkyl t-butry nitroxides--A new Scale for electronegativity of perfluoro-n-alkyl groups Research on Chemical Intermediates 2000, 26, 587~597.

61. AM1研究苯及取代苯甲酸亚硝酰酯热分解反应 江西师范大学学报(自然科学版) 1998,3, 235

62. 硅烷偶联剂KBM602的合成工艺研究 江西师范大学学报 1998, 2,153

63. 亚硝酸过氧酯热分解反应的量子化学研究 江西师范大学学报(自然科学版) 1998,1, 61

64. Quantum chemical study on the thermal Diels-Alder reaction of cyclohexadiene and methyl crotonate Chinese Journal of Chemistry 1997, 1,21~24

65. 苯基及取代苯基四唑异构反应的量子化学研究 物理化学学报 1997, 12, 1115~1118.

66. AM1法研究取代乙烯与环己-1,3-二烯热加成 物理化学学报 1997, 6, 532~536.

67. O-酰基羟胺衍生物的热分解反应的理论研究 江西师范大学学报(自然科学版) 1997, 4, 354

68. 羧酸亚硝酰酯热分解反应的量子化学研究 江西师范大学学报(自然科学版) 1997, 1, 68.

69. 甲基(γ-氯丙基)二氯硅烷的制备工艺研究 江西师范大学学报(自然科学版) 1996,4,294~298.

70. n-alkyl perfluoroacyl nitroxides─Epr studies on electron transfer reaction of perfluorodiacyl peroxides with O-benzoyl-N-alkylhydroxylamines Journal of fluorine chemistry 1993,61, 45-49.

71. Electron paramagnetic resonance studies on the generation and solvation of n- heptfluoropropyl t-butyl nitroxide Journal of fluorine chemistry, 1993, 61, 171-177.

72. 三氟甲基叔丁基氮氧自由基的超精细偶合常数与溶剂极性参数的相关研究 高等学校化学学报 1992,13(11),1448~1451. (SCI)

73. 烷基-全氟烷基酰基氮氧自由基──全氟酰基过氧化物与脂肪族伯、仲胺单电子转移反应的EPR研究 高等学校化学学报 1992,13(2), 209-213. (SCI)

74. new method for generation of t-butyl perfluoroalkyl nitroxides Chinese Chemical Letter, 1992, 3, 611~612.

75. EPR Studies on Electron Transfer between O-benzoyl-N-alkylhydroxyl Aimines and Perfluorocyl Peroxides Research on Chemical Intermediates, 1992, 18, 1-17.

==参考来源==
[[Category:教授]] [[Category:科学家]][[Category:政协委员]]